New progress in the synthesis route and purification technology of dibutyltin dilaurate

New progress in the synthesis route and purification technology of dibutyltin dilaurate

Introduction

Dibutyltin dilaurate (DBTDL), as an efficient catalyst and stabilizer, has been widely used in many industrial fields. This article will review the new progress in the synthesis route of DBTDL and its purification technology, aiming to provide a reference for researchers and enterprises to improve the production efficiency and product quality of DBTDL.

1. Synthetic route of dibutyltin dilaurate

1. Traditional synthesis methods

   • Reaction principle: The traditional synthesis method mainly prepares DBTDL through the esterification reaction of dibutyltin oxide and lauric acid.
   • Reaction steps:
     1. Raw material preparation: Mix dibutyltin oxide and lauric acid in a certain proportion.
     2. Esterification reaction: At a certain temperature (usually 120-150°C), the raw materials are thoroughly mixed by stirring to carry out esterification reaction.
     3. Post-treatment: After the reaction is completed, the product is purified through filtration, washing, drying and other steps.

2. Improved synthesis method

   • Catalyst usage: In order to improve reaction efficiency, catalysts, such as sulfuric acid, sodium hydroxide, etc., can be added during the reaction process.
   • Optimization of reaction conditions: Improve the selectivity and yield of the reaction by optimizing conditions such as reaction temperature, time and pressure.
   • Continuous reaction: Use continuous reaction devices to improve production efficiency and reduce the occurrence of side reactions.

3. Novel synthesis method

   • Microwave-assisted synthesis: Use microwave heating technology to increase reaction rate and yield. Microwave heating can achieve rapid temperature rise, reduce reaction time, and improve reaction selectivity.
   • Ultrasound-assisted synthesis: Use the cavitation effect of ultrasonic waves to promote the mixing and reaction of raw materials and improve reaction efficiency.
   • Solvothermal synthesis: Using solvothermal method to synthesize DBTDL under high temperature and high pressure conditions can reduce the occurrence of side reactions and improve the purity of the product.

II. Purification technology of dibutyltin dilaurate

1. Traditional purification methods

   • Distillation: Remove unreacted raw materials and by-products through vacuum distillation or molecular distillation to improve the purity of the product.
   • Extraction: Use organic solvents (such as ethanol, methanol, etc.) to extract the crude product to remove impurities.
   • Filtration: Remove insoluble impurities, such as catalyst residues, etc. through filtration.
   • Recrystallization: Dissolve the crude product in a suitable solvent and purify the product by recrystallization.

2. Improved purification method

   • Membrane separation technology: Use membrane separation technologies such as nanofiltration and reverse osmosis to remove small molecule impurities and solvents and improve the purity of the product.
   • Ion exchange: Remove metal ions and other impurities from the product through ion exchange resin.
   • Adsorption: Use adsorbents such as activated carbon and molecular sieves to remove organic impurities and moisture in the product.

3. New purification technology

   • Supercritical fluid extraction: Use supercritical carbon dioxide as a solvent to extract and purify DBTDL. Supercritical fluids have good dissolving ability and low toxicity, and can effectively remove impurities.
   • Electrodialysis: Through electrodialysis technology, electrolytes and small molecule impurities in the product are removed to improve the purity of the product.
   • Molecular Imprinting Technology: Use molecularly imprinted polymers (MIPs) to selectively adsorb and purify DBTDL to improve the purity and selectivity of the product.

3. New progress in synthetic pathways and purification technologies

1. Microwave-assisted synthesis

   • Research Progress: Microwave-assisted synthesis technology has made significant progress in the preparation of DBTDL. Research shows that microwave heating can significantly shorten the reaction time and improve the selectivity and yield of the reaction.
   • Practical application: Some companies have adopted microwave-assisted synthesis technology in production to achieve efficient and low-cost DBTDL production.

2. Ultrasound-assisted synthesis

   • Research Progress: Ultrasound-assisted synthesis technology has also made important progress in the preparation of DBTDL. The cavitation effect of ultrasonic waves can promote the mixing and reaction of raw materials and improve reaction efficiency.
   • Practical application: Ultrasound-assisted synthesis technology has been applied to laboratory-scale DBTDL synthesis, showing good application prospects.

3. Solvothermal Synthesis

   • Research Progress: Solvothermal synthesis technology has demonstrated unique advantages in the preparation of DBTDL. Research shows that solvothermal method can reduce the occurrence of side reactions and improve the purity of the product.
   • Practical Application: Solvothermal synthesis technology is already being tested.It has been successful in large-scale DBTDL synthesis and is expected to be used in industrial production in the future.

4. Supercritical Fluid Extraction

   • Research Progress: Supercritical fluid extraction technology has demonstrated significant advantages in the purification of DBTDL. Research shows that supercritical carbon dioxide can effectively remove impurities in products and improve product purity.
   • Practical application: Some companies have adopted supercritical fluid extraction technology in production to achieve efficient and environmentally friendly DBTDL purification.

5. Molecular Imprinting Technology

   • Research Progress: Molecular imprinting technology has demonstrated unique selectivity and efficiency in the purification of DBTDL. Studies have shown that molecularly imprinted polymers can selectively adsorb and purify DBTDL, improving the purity and selectivity of the product.
   • Practical application: Molecular imprinting technology has been applied to laboratory-scale DBTDL purification, showing good application prospects.

4. Conclusion and Outlook

Through a review of new developments in the synthesis routes and purification technologies of dibutyltin dilaurate, we draw the following conclusions:

1. Synthesis path: Although traditional synthesis methods are mature, they have problems such as long reaction time and many side reactions. New synthesis methods, such as microwave-assisted synthesis, ultrasound-assisted synthesis and solvothermal synthesis, can significantly improve reaction efficiency and yield and reduce the occurrence of side reactions.
2. Purification technology: Traditional purification methods such as distillation, extraction and filtration, although effective, have problems such as high energy consumption and complex operations. New purification technologies such as supercritical fluid extraction, electrodialysis and molecular imprinting technology can significantly improve the purity and selectivity of products and reduce energy consumption and environmental pollution.

Future research directions will focus more on developing more efficient and environmentally friendly synthesis and purification technologies to reduce the impact on the environment. In addition, by further optimizing the reaction conditions and purification process, the production efficiency and product quality of DBTDL can be further improved, providing technical support for the development of related industries.

5. Suggestions

1. Increase R&D investment: Companies should increase R&D investment in new synthesis and purification technologies to improve the competitiveness of their products.
2. Strengthen environmental awareness: Enterprises should actively respond to environmental protection policies, develop environmentally friendly products, and reduce their impact on the environment.
3. Technical training: Provide technical training to technical personnel on new technologies to ensure that they master advanced synthesis and purification technologies.
4. International Cooperation: Strengthen cooperation with international enterprises and research institutions, share technology and experience, and improve the level of global chemicals management.

Extended reading:

cyclohexylamine

Tetrachloroethylene Perchloroethylene CAS:127-18-4

NT CAT DMDEE

NT CAT PC-5

N-Methylmorpholine

4-Formylmorpholine

Toyocat TE tertiary amine catalyst Tosoh

Toyocat RX5 catalyst trimethylhydroxyethyl ethylenediamine Tosoh

NT CAT DMP-30

NT CAT DMEA